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[Cp*RuPb11]3−and [Cu@Cp*RuPb11]2−: centered and non-centered transition-metal substituted zintl icosahedra

dc.contributor.authorLi, Ai-Min
dc.contributor.authorWang, Yi
dc.contributor.authorZavalij, Peter Y.
dc.contributor.authorChen, Fu
dc.contributor.authorMuñoz-Castro, Alvaro
dc.contributor.authorEichhorn, Bryan W.
dc.date.accessioned2020-09-28T14:38:24Z
dc.date.available2020-09-28T14:38:24Z
dc.date.issued2020-09-21
dc.identifier10.1039/d0cc03656k
dc.identifier.issn13597345
dc.identifier.urihttps://hdl.handle.net/20.500.12728/6914
dc.description.abstractCluster anions [Cp*RuPb11]3−(1) and [Cu@Cp*RuPb11]2−(2) represent the first vertex-substituted zintl icosahedra and1is the first non-centered zintl icosahedron isolated in the condensed phase. Complexes1and2are both 12-vertex, 26-electroncloso-clusters withC5vpoint symmetry and are static on the207Pb NMR time scale in solution.es_ES
dc.language.isoenes_ES
dc.publisherRoyal Society of Chemistryes_ES
dc.title[Cp*RuPb11]3−and [Cu@Cp*RuPb11]2−: centered and non-centered transition-metal substituted zintl icosahedraes_ES
dc.typeArticlees_ES


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