[Cp*RuPb11]3−and [Cu@Cp*RuPb11]2−: centered and non-centered transition-metal substituted zintl icosahedra
Autor
Li, Ai-Min
Wang, Yi
Zavalij, Peter Y.
Chen, Fu
Muñoz-Castro, Alvaro
Eichhorn, Bryan W.
Resumen
Cluster anions [Cp*RuPb11]3−(1) and [Cu@Cp*RuPb11]2−(2) represent the first vertex-substituted zintl icosahedra and1is the first non-centered zintl icosahedron isolated in the condensed phase. Complexes1and2are both 12-vertex, 26-electroncloso-clusters withC5vpoint symmetry and are static on the207Pb NMR time scale in solution.
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