Listar Artículos científicos por autor "Qiao, Lei"
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Article
A sandwich-type cluster containing Ge@Pd3 planar fragment flanked by aromatic nonagermanide caps (2020)
Xu, Honglei; Tkachenko, Nikolay V.; Wang, Zichuan; Chen, Weixing; Qiao, Lei; Muñoz-Castro, Alvaro; Boldyrev, Alexander I.; Sun, Zhongming (Nature Research, 2020-12-01)Sandwich-type clusters with the planar fragment containing a heterometallic sheet have remained elusive. In this work, we introduce the [K(2,2,2-crypt)]4{(Ge9)2[η6-Ge(PdPPh3)3]} complex that contains a heterometallic ... -
Article
[As3M(As3Pb3)]3− (M = Nb, Ta): Ternary Heterometallic Clusters with Early Transition Metal Atoms and Aromatic [Pb3]2− (2021)
Shu, Congcong; Qiao, Lei; Muñoz-Castro, Alvaro; Sun, Zhongming (Shanghai Institute of Organic Chemistry, 2021)Two ternary clusters, [As3Nb(As3Pb3)]3− 1 and [As3Ta(As3Pb3)]3− 2, were directly extracted from “K8NbPbAs5” and “K8TaPbAs5” intermetallic solid in the presence of ethylenediamine and 2.2.2-crypt, respectively. Both 1 and ... -
Article
[Bi6Mo3(CO)9]4−: a multiple local σ-aromatic cluster containing a distorted Bi6triangular prism (2021)
Qiao, Lei; Chen, Dandan; Zhu, Jun; Muñoz-Castro, Alvaro; Sun, Zhongming (Royal Society of Chemistry, 2021-04-18)The first Zintl cluster containing a distorted Bi6triangular prism, [Bi6Mo3(CO)9]4−, has been synthesized and structurally characterized. Quantum chemical calculations indicated that the distorted cage cluster features ... -
Article
Ternary aromatic and anti-aromatic clusters derived from the hypho species [Sn2Sb5]3− (2021)
Xu, Yuhe; Tkachenko, Nikolay V.; Popov, Ivan A.; Qiao, Lei; Muñoz-Castro, Álvaro; Boldyrev, Alexander I.; Sun, Zhongming (Nature Research, 2021-12)Heterometallic clusters have attracted broad interests in the synthetic chemistry due to their various coordination modes and potential applications in heterogeneous catalysis. Here we report the synthesis, experimental, ...