[Bi6Mo3(CO)9]4−: a multiple local σ-aromatic cluster containing a distorted Bi6triangular prism
Autor
Qiao, Lei
Chen, Dandan
Zhu, Jun
Muñoz-Castro, Alvaro
Sun, Zhongming
Resumen
The first Zintl cluster containing a distorted Bi6triangular prism, [Bi6Mo3(CO)9]4−, has been synthesized and structurally characterized. Quantum chemical calculations indicated that the distorted cage cluster features multiple local σ-aromaticity.
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