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Facile synthesis of a luminescent copper(I) coordination polymer containing a flexible benzotriazole-based ligand: An effective catalyst for three-component azide-alkyne cycloaddition
dc.contributor.author | Nuñez-Dallos N. | |
dc.contributor.author | Muñoz-Castro A. | |
dc.contributor.author | Fuentealba M. | |
dc.contributor.author | Pérez E.G. | |
dc.contributor.author | Hurtado J.J. | |
dc.date.accessioned | 2020-09-02T22:24:38Z | |
dc.date.available | 2020-09-02T22:24:38Z | |
dc.date.issued | 2019 | |
dc.identifier | 10.1016/j.ica.2019.119136 | |
dc.identifier.citation | 498, , - | |
dc.identifier.issn | 00201693 | |
dc.identifier.uri | https://hdl.handle.net/20.500.12728/5581 | |
dc.description | A straightforward method for the synthesis of a new luminescent copper(I) coordination polymer (CP) containing the ligand 1,3-bis(1H-benzotriazol-1-ylmethyl)benzene (L) through a self-assembly process with copper(I) iodide is reported. The CP was characterized by infrared, NMR, UV–Vis and photoluminescence spectroscopy, high resolution mass spectrometry (ESI), elemental and thermogravimetric analyses, single-crystal and powder X-ray diffraction, and relativistic density functional theory calculations. Furthermore, this one-dimensional copper(I) benzotriazole-based coordination polymer catalyzed the three-component azide-alkyne cycloaddition reaction to obtain 1,4-disubstituted 1,2,3-triazoles in good to excellent yields (up to 95%) from organic halides, sodium azide and terminal alkynes. © 2019 Elsevier B.V. | |
dc.language.iso | en | |
dc.publisher | Elsevier S.A. | |
dc.subject | Azide-alkyne cycloaddition | |
dc.subject | Catalysis | |
dc.subject | Click chemistry | |
dc.subject | Copper(I) coordination polymer | |
dc.subject | Luminescence | |
dc.subject | Benzene refining | |
dc.subject | Catalysis | |
dc.subject | Chelation | |
dc.subject | Cycloaddition | |
dc.subject | Density functional theory | |
dc.subject | Hydrocarbons | |
dc.subject | Ligands | |
dc.subject | Luminescence | |
dc.subject | Mass spectrometry | |
dc.subject | Photoluminescence spectroscopy | |
dc.subject | Polymers | |
dc.subject | Single crystals | |
dc.subject | Sodium Azide | |
dc.subject | Thermogravimetric analysis | |
dc.subject | Azide-alkyne cycloaddition | |
dc.subject | Click chemistry | |
dc.subject | Coordination Polymers | |
dc.subject | High resolution mass spectrometry | |
dc.subject | Relativistic density functional theory | |
dc.subject | Self assembly process | |
dc.subject | Single-crystal and powder | |
dc.subject | Straight-forward method | |
dc.subject | Copper compounds | |
dc.title | Facile synthesis of a luminescent copper(I) coordination polymer containing a flexible benzotriazole-based ligand: An effective catalyst for three-component azide-alkyne cycloaddition | |
dc.type | Article |