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dc.contributor.authorMuñoz-Castro A.
dc.date.accessioned2020-09-02T22:24:08Z
dc.date.available2020-09-02T22:24:08Z
dc.date.issued2018
dc.identifier10.1039/c7cp08323h
dc.identifier.citation20, 5, 3433-3437
dc.identifier.issn14639076
dc.identifier.urihttps://hdl.handle.net/20.500.12728/5510
dc.descriptionThe formation of carbon nanobelt made exclusively from fused benzene rings has recently been achieved. Our results reveal an interesting shift from a local aromatic character constrained in each of the six aromatic Clar sextets (6π-electron circuit) to a global aromatic character in charged species (+2 and -2) involving the overall π-circuit from the molecular nanobelt. This demonstrates the suppression of the local aromatic character in favor of a global aromaticity by selecting the oxidation state of the carbon nanobelt, giving rise to a shielding cone extended within the structure. © 2018 the Owner Societies.
dc.language.isoen
dc.publisherRoyal Society of Chemistry
dc.titleLocal and global aromaticity in a molecular carbon nanobelt: Insights from magnetic response properties in neutral and charged species
dc.typeArticle


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