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dc.contributor.authorFlores M.E.
dc.contributor.authorSano N.
dc.contributor.authorAraya-Hermosilla R.
dc.contributor.authorShibue T.
dc.contributor.authorOlea A.F.
dc.contributor.authorNishide H.
dc.contributor.authorMoreno-Villoslada I.
dc.date.accessioned2020-09-02T22:17:52Z
dc.date.available2020-09-02T22:17:52Z
dc.date.issued2015
dc.identifier10.1016/j.dyepig.2014.07.015
dc.identifier.citation112, , 262-273
dc.identifier.issn01437208
dc.identifier.urihttps://hdl.handle.net/20.500.12728/4481
dc.descriptionWith the aim of achieving supramolecular structures containing dyes with controlled state of aggregation, the formation of ternary complexes between 5,10,15,20-tetrakis-(4-sulfonatophenyl)-porphyrin, poly(decylviologen), and sulfobutylether-β-cyclodextrin at low excess of the cyclodextrin is described. By controlling the stoichiometry of the reactants, both non-fluorescent H-aggregates of the dye and stabilized fluorescent monomers may be obtained. The dye undergoes self-aggregation in the presence of the flexible, cationic polymer, and by addition of the negatively charged cyclodextrin the aggregates are cleaved. The cyclodextrin primarily induces the inclusion of 5,10,15,20-tetrakis-(4-sulfonatophenyl)-porphyrin in its cavity, and the ensemble is stabilized by the polymer by means of electrostatic, hydrophobic, and/or aromatic-aromatic interactions. The ternary complex thus produced tends to nanofiber formation, as seen by FE-TEM. © 2014 Elsevier Ltd. All rights reserved.
dc.language.isoen
dc.publisherElsevier Ltd
dc.subject5,10,15,20-Tetrakis-(4-sulfonatophenyl)-porphyrin
dc.subjectKinetics
dc.subjectMolecular assembly
dc.subjectPoly(decylviologen)
dc.subjectSulfobutylether-β- cyclodextrin
dc.subjectTernary complex
dc.subjectAgglomeration
dc.subjectAggregates
dc.subjectAromatic compounds
dc.subjectAssociation reactions
dc.subjectEnzyme kinetics
dc.subjectFluorescence
dc.subjectPorphyrins
dc.subjectAromatic-aromatic interactions
dc.subjectCationic polymers
dc.subjectMolecular assembly
dc.subjectNegatively charged
dc.subjectPoly(decylviologen)
dc.subjectSelf-associations
dc.subjectSupramolecular structure
dc.subjectTernary complex
dc.subjectCyclodextrins
dc.titleSelf-association of 5,10,15,20-tetrakis-(4-sulfonatophenyl)-porphyrin tuned by poly(decylviologen) and sulfobutylether-β-cyclodextrin
dc.typeArticle


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