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dc.contributor.authorTreto-Suárez, Manuel A.
dc.contributor.authorDiaz-Uribe, Carlos
dc.contributor.authorVallejo, William
dc.contributor.authorZarate, Ximena
dc.contributor.authorSchott, Eduardo
dc.date.accessioned2024-04-10T01:43:20Z
dc.date.available2024-04-10T01:43:20Z
dc.date.issued2023
dc.identifier10.1021/acsomega.3c06471
dc.identifier.issn24701343
dc.identifier.urihttps://hdl.handle.net/20.500.12728/10670
dc.description.abstractA new polyaniline derivative was prepared to study the formation of quinoid-diimine units in its polymer. The monomer and polymer were experimentally and theoretically characterized. Both polymers have one or two electron-withdrawing groups as side substituents. The polymers’ quinoid-diimine unit composition is affected by the electron-withdrawing side groups of aniline. The presence of the quinoid-diimine group diminished for the two electron-withdrawing groups of aniline. The polymer conductivity is different than with respect to polyemeraldine, associated with the quinoid-diimine units’ composition. The quinoid-diimine composition is strongly increased in the polymer containing one electron-withdrawing group. Moreover, the polymer presented good solubility in organic solvents and moderate thermal stability. © 2023 The Authors. Published by American Chemical Society.es_ES
dc.description.sponsorshipFondo Nacional de Desarrollo Científico y Tecnológico, FONDECYT, (1201880, 1231194, 3210271, ACT210057, ANID/FONDAP/1523A0006)es_ES
dc.language.isoenes_ES
dc.publisherAmerican Chemical Societyes_ES
dc.titleNew Polyaniline Derivative with Two Central Ester Groups: Synthesis, Characterization, and Theoretical Studyes_ES
dc.typeArticlees_ES


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