Fluorinated tris(pyridyl)borate ligand support on coinage metals
Autor
Vanga, Mukundam
Muñoz-Castro, Álvaro
Dias, H. V. Rasika
Resumen
A useful ligand involving three pyridyl donor arms and fluorocarbon substituents surrounding the coordination pocket has been assembled and utilized in coinage metal chemistry. This tris(pyridyl)borate serves as an excellent ligand support for the stabilization of ethylene complexes of copper, silver and gold.
Colecciones
Ítems relacionados
Mostrando ítems relacionados por Título, autor o materia.
-
Article
Coinage Metal Superatomic Cores: Insights into Their Intrinsic Stability and Optical Properties from Relativistic DFT Calculations (2020)
Gam F.; Paez-Hernandez D.; Arratia-Perez R.; Liu C.W.; Kahlal S.; Saillard J.-Y.; Muñoz-Castro A. (Wiley-VCH Verlag, 2017) -
Article
Terminal and internal alkyne complexes and azide-alkyne cycloaddition chemistry of copper(I) supported by a fluorinated bis(pyrazolyl)borate (2022)
Noonikara-Poyil, Anurag; Muñoz-Castro, Álvaro; Dias, H. V.Rasika (MDPI, 2022-01-01)Copper plays an important role in alkyne coordination chemistry and transformations. This report describes the isolation and full characterization of a thermally stable, copper(I) acetylene complex using a highly fluorinated ... -
Article
Isolable 1-Butene Copper(I) Complexes and 1-Butene/Butane Separation Using Structurally Adaptable Copper Pyrazolates (2020)
Elashkar, Ahmed H.; Parasar, Devaborniny; Munõz-Castro, Alvaro; Doherty, Cara M.; Cowan, Matthew G.; Dias, H. V.Rasika (Wiley-VCH Verlag, 2020-11-26)Non-porous small molecule adsorbents such as {[3,5-(CF3)2Pz]Cu}3 (where Pz=pyrazolate) are an emerging class of materials that display attractive features for ethene−ethane separation. This work examines the chemistry of ...