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Bridging Aromatic/Antiaromatic Units: Recent Advances in Aromaticity and Antiaromaticity in Main-group and Transition-Metal Clusters from Bonding and Magnetic Analyses
dc.contributor.author | Tkachenko, Nikolay V. | |
dc.contributor.author | Popov, Ivan A. | |
dc.contributor.author | Kulichenko, Maksim | |
dc.contributor.author | Fedik, Nikita S. | |
dc.contributor.author | Sun, Zhongming | |
dc.contributor.author | Muñoz-Castro, Álvaro | |
dc.contributor.author | Boldyrev, Alexander I. | |
dc.date.accessioned | 2021-09-10T04:04:06Z | |
dc.date.available | 2021-09-10T04:04:06Z | |
dc.date.issued | 2021 | |
dc.identifier | 10.1002/ejic.202100519 | |
dc.identifier.issn | 14341948 | |
dc.identifier.uri | https://hdl.handle.net/20.500.12728/9517 | |
dc.description.abstract | Synthetic exploration and theoretical characterization of metal clusters are actively developing branches of modern inorganic chemistry. Advances in these areas constantly expand the rich structural diversity of viable species, allowing a detailed study of the fundamental characteristics of bench-stable compounds. In this minireview, we summarize recent achievements in synthesis and computational analyses of main-group and heterometallic clusters containing multiple aromatic/antiaromatic units. These systems range from bare clusters to ligand-decorated aggregates, providing a fundamental understanding of the aromaticity and antiaromaticity concepts in species exhibiting unprecedented shapes and composition. The review gives a comprehensive summary of bonding and magnetic response properties of such systems deciphered from the Adaptive Natural Density Partitioning (AdNDP) approach and induced magnetic field analyses. | es_ES |
dc.language.iso | en | es_ES |
dc.publisher | John Wiley and Sons Inc | es_ES |
dc.subject | Antiaromaticity | es_ES |
dc.subject | Aromaticity | es_ES |
dc.subject | Clusters | es_ES |
dc.subject | Main-group | es_ES |
dc.subject | Transition-metal | es_ES |
dc.title | Bridging Aromatic/Antiaromatic Units: Recent Advances in Aromaticity and Antiaromaticity in Main-group and Transition-Metal Clusters from Bonding and Magnetic Analyses | es_ES |
dc.type | Article | es_ES |