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dc.contributor.authorCastillo-Toraya, Gabriela
dc.contributor.authorOrozco-Ic, Mesías
dc.contributor.authorDzib, Eugenia
dc.contributor.authorZárate, Ximena P.
dc.contributor.authorOrtíz-Chi, Filiberto
dc.contributor.authorCui, Zhonghua
dc.contributor.authorBarroso, Jorge
dc.contributor.authorMerino, Gabriel
dc.date.accessioned2021-06-08T03:44:39Z
dc.date.available2021-06-08T03:44:39Z
dc.date.issued2021-05-21
dc.identifier10.1039/d1sc01325d
dc.identifier.issn20416520
dc.identifier.urihttps://hdl.handle.net/20.500.12728/8907
dc.description.abstractAmong the list of planar tetracoordinate atoms, fluorine is missing. So far, there are no theoretical or experimental reports suggesting their existence. Herein, we introduce the first six combinations (FIn4+, FTl4+, FGaIn3+, FIn2Tl2+, FIn3Tl+, and FInTl3+) whose global minima contain a planar tetracoordinate fluorine. The bonding analyses indicate that the interactions between the fluorine and the peripheral atoms are significantly electrostatic, which is also reflected in the electronic delocalization. As opposed to other planar tetracoordinate systems with carbon, nitrogen, or oxygen atoms, the fluorine in the ptFs does not act as a σ-acceptor, restraining any back-donation. On the other hand, σ-electrons show a diatropic response, which would characterize these clusters as σ-aromatic.es_ES
dc.language.isoenes_ES
dc.publisherRoyal Society of Chemistryes_ES
dc.titlePlanar tetracoordinate fluorine atomses_ES
dc.typeArticlees_ES


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