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Gold(i) ethylene complexes supported by electron-rich scorpionates

dc.contributor.authorWu, Jiang
dc.contributor.authorNoonikara-Poyil, Anurag
dc.contributor.authorMuñoz-Castro, Alvaro
dc.contributor.authorDias, H. V. Rasika
dc.date.accessioned2021-03-04T15:01:26Z
dc.date.available2021-03-04T15:01:26Z
dc.date.issued2021
dc.identifier10.1039/d0cc07717h
dc.identifier.issn13597345
dc.identifier.urihttps://hdl.handle.net/20.500.12728/8656
dc.description.abstractEthylene complexes of gold(i) have been stabilized by electron-rich, κ2-bound tris(pyrazolyl)borate ligands. Large up-field shifts of olefinic carbon NMR resonances and relatively long C distances of gold bound ethylene are indicative of significant Au(i) → ethylene π-backbonding relative to the analog supported by a weakly donating ligand, consistent with the computational data.es_ES
dc.language.isoenes_ES
dc.publisherRoyal Society of Chemistryes_ES
dc.titleGold(i) ethylene complexes supported by electron-rich scorpionateses_ES
dc.typeArticlees_ES


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