Synthesis and characterization of N-heterocyclic carbene-M⋯OEt2complexes (M = Cu, Ag, Au). Analysis of solvated auxiliary-ligand free [(NHC)M]+species

dc.contributor.author	Munõz-Castro, Alvaro
dc.contributor.author	Wang, Guocang
dc.contributor.author	Ponduru, Tharun Teja
dc.contributor.author	Dias, H. V.Rasika
dc.date.accessioned	2021-03-03T12:53:46Z
dc.date.available	2021-03-03T12:53:46Z
dc.date.issued	2021-01-14
dc.identifier	10.1039/d0cp05222a
dc.identifier.issn	14639076
dc.identifier.uri	https://hdl.handle.net/20.500.12728/8640
dc.description.abstract	We report the synthesis, characterization and computational analysis of coinage metal-ether complexes supported by N-heterocyclic carbenes (NHC), SIPr and Et2CAAC. The related water adducts are also included. The [(NHC)M]+(M = Cu, Ag, Au) species show the noteworthy ability to bind Et2O and H2O. This interaction towards Et2O and H2O is partly ascribed to a σ-hole bonding with an almost linear disposition, taking advantage of the enhanced σ-hole potential evaluated for such [(NHC)M]+ species. This enhanced ability is larger than those found for non-covalent interactions involving main group species.	es_ES
dc.language.iso	en	es_ES
dc.publisher	Royal Society of Chemistry	es_ES
dc.subject	Aromatic compounds	es_ES
dc.subject	Praseodymium compounds	es_ES
dc.title	Synthesis and characterization of N-heterocyclic carbene-M⋯OEt2complexes (M = Cu, Ag, Au). Analysis of solvated auxiliary-ligand free [(NHC)M]+species	es_ES
dc.type	Article	es_ES

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