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All-metal σ-antiaromaticity in dimeric cluster anion {[CuGe9Mes]2}4-

dc.contributor.authorWang Z.-C.
dc.contributor.authorTkachenko N.V.
dc.contributor.authorQiao L.
dc.contributor.authorMatito E.
dc.contributor.authorMatito E.
dc.contributor.authorMuñoz-Castro A.
dc.contributor.authorBoldyrev A.I.
dc.contributor.authorSun Z.-M.
dc.date.accessioned2020-09-02T22:30:33Z
dc.date.available2020-09-02T22:30:33Z
dc.date.issued2020
dc.identifier10.1039/d0cc02525a
dc.identifier.citation56, 48, 6583-6586
dc.identifier.issn13597345
dc.identifier.urihttps://hdl.handle.net/20.500.12728/6629
dc.descriptionIn this work, we report a dimeric cluster anion, {[CuGe9Mes]2}4-, which was isolated as the [K(2,2,2-crypt)]+ salt and characterized by using single-crystal X-ray diffraction and ESI mass spectroscopy. The title cluster represents the first locally σ-antiaromatic compound in the solid state, as well as the first heteroatomic antiaromatic compound. This journal is © The Royal Society of Chemistry.
dc.language.isoen
dc.publisherRoyal Society of Chemistry
dc.titleAll-metal σ-antiaromaticity in dimeric cluster anion {[CuGe9Mes]2}4-
dc.typeArticle


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