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Novel ruthenium-silver PTA-based polymers and their behavior in water

dc.contributor.authorSierra-Martin B.
dc.contributor.authorSerrano-Ruiz M.
dc.contributor.authorScalambra F.
dc.contributor.authorFernandez-Barbero A.
dc.contributor.authorRomerosa A.
dc.date.accessioned2020-09-02T22:28:15Z
dc.date.available2020-09-02T22:28:15Z
dc.date.issued2019
dc.identifier10.3390/polym11081249
dc.identifier.citation11, 8, -
dc.identifier.issn20734360
dc.identifier.urihttps://hdl.handle.net/20.500.12728/6255
dc.descriptionNew coordination polymers based on two metal-containing moieties Ru-Ag are synthesized: Na[RuCpX(PTA)-μ-(PTA)-1κP:2κ2N-AgX2]∞ (X = Cl (1), Br (2), I (3)). Characterization is performed by NMR, UV-visible and FT-IR spectroscopy, optical-electron microscopy, and elemental analyses (C, H, N, S). Light scattering is employed to characterize the colloidal particles growth by polymer self-assembling. These structures are stable over a broad range of pH and exhibit thermally-driven swelling, thus resembling a typical thermosensitive hydrogel. © 2019 by the authors.
dc.language.isoen
dc.publisherMDPI AG
dc.subjectLight scattering
dc.subjectOrganometallic
dc.subjectPolymer swelling
dc.subjectPTA
dc.subjectRuthenium complexes
dc.subjectBinary alloys
dc.subjectLight scattering
dc.subjectOrganometallics
dc.subjectRuthenium alloys
dc.subjectRuthenium compounds
dc.subjectSilver
dc.subjectSilver alloys
dc.subjectSodium alloys
dc.subjectColloidal particle
dc.subjectCoordination Polymers
dc.subjectFTIR spectroscopy
dc.subjectOptical electron microscopy
dc.subjectPolymer swelling
dc.subjectRuthenium complexes
dc.subjectThermally driven
dc.subjectThermo-sensitive hydrogel
dc.subjectPolymers
dc.titleNovel ruthenium-silver PTA-based polymers and their behavior in water
dc.typeArticle


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