First exfoliated Ru-Ru-Au organometallic polymer with layered structure

dc.contributor.author	Scalambra F.
dc.contributor.author	Sierra-Martin B.
dc.contributor.author	Serrano-Ruiz M.
dc.contributor.author	Fernandez-Barbero A.
dc.contributor.author	Romerosa A.
dc.date.accessioned	2020-09-02T22:28:07Z
dc.date.available	2020-09-02T22:28:07Z
dc.date.issued	2020
dc.identifier	10.1039/d0cc04325g
dc.identifier.citation	56, 66, 9441-9444
dc.identifier.issn	1364548X
dc.identifier.uri	https://hdl.handle.net/20.500.12728/6208
dc.description	A new water soluble heterometallic polymeric complex [{(PTA)2CpRu-μ-CN-1κC:2κ2N-RuCp(PTA)2}-μ-{Au(CN)4}4]n·2H2O (1) is synthesized and characterized by single crystal X-ray diffraction. This complex self-assembles forming 3D polymeric structures with large scale hexagonal conformation. They also organize as 3D stacks of polymer sandwiches that can be exfoliated providing mono heterometallic-3D layers, as shown by electron microscopy. Regarding the polymer dynamics, quasi-elastic neutron scattering shows a transition from vibrational Debye-Waller behaviour to a more dynamically active state as a result of the loss of structural water molecules.
dc.language.iso	en
dc.publisher	NLM (Medline)
dc.title	First exfoliated Ru-Ru-Au organometallic polymer with layered structure
dc.type	Article

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