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Facile synthesis of a luminescent copper(I) coordination polymer containing a flexible benzotriazole-based ligand: An effective catalyst for three-component azide-alkyne cycloaddition

dc.contributor.authorNuñez-Dallos N.
dc.contributor.authorMuñoz-Castro A.
dc.contributor.authorFuentealba M.
dc.contributor.authorPérez E.G.
dc.contributor.authorHurtado J.J.
dc.date.accessioned2020-09-02T22:24:38Z
dc.date.available2020-09-02T22:24:38Z
dc.date.issued2019
dc.identifier10.1016/j.ica.2019.119136
dc.identifier.citation498, , -
dc.identifier.issn00201693
dc.identifier.urihttps://hdl.handle.net/20.500.12728/5581
dc.descriptionA straightforward method for the synthesis of a new luminescent copper(I) coordination polymer (CP) containing the ligand 1,3-bis(1H-benzotriazol-1-ylmethyl)benzene (L) through a self-assembly process with copper(I) iodide is reported. The CP was characterized by infrared, NMR, UV–Vis and photoluminescence spectroscopy, high resolution mass spectrometry (ESI), elemental and thermogravimetric analyses, single-crystal and powder X-ray diffraction, and relativistic density functional theory calculations. Furthermore, this one-dimensional copper(I) benzotriazole-based coordination polymer catalyzed the three-component azide-alkyne cycloaddition reaction to obtain 1,4-disubstituted 1,2,3-triazoles in good to excellent yields (up to 95%) from organic halides, sodium azide and terminal alkynes. © 2019 Elsevier B.V.
dc.language.isoen
dc.publisherElsevier S.A.
dc.subjectAzide-alkyne cycloaddition
dc.subjectCatalysis
dc.subjectClick chemistry
dc.subjectCopper(I) coordination polymer
dc.subjectLuminescence
dc.subjectBenzene refining
dc.subjectCatalysis
dc.subjectChelation
dc.subjectCycloaddition
dc.subjectDensity functional theory
dc.subjectHydrocarbons
dc.subjectLigands
dc.subjectLuminescence
dc.subjectMass spectrometry
dc.subjectPhotoluminescence spectroscopy
dc.subjectPolymers
dc.subjectSingle crystals
dc.subjectSodium Azide
dc.subjectThermogravimetric analysis
dc.subjectAzide-alkyne cycloaddition
dc.subjectClick chemistry
dc.subjectCoordination Polymers
dc.subjectHigh resolution mass spectrometry
dc.subjectRelativistic density functional theory
dc.subjectSelf assembly process
dc.subjectSingle-crystal and powder
dc.subjectStraight-forward method
dc.subjectCopper compounds
dc.titleFacile synthesis of a luminescent copper(I) coordination polymer containing a flexible benzotriazole-based ligand: An effective catalyst for three-component azide-alkyne cycloaddition
dc.typeArticle


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