The shielding cone in spherical aromatic structures: Insights from models for spherical 2(N + 1)2 aromatic fullerenes

dc.contributor.author	Muñoz-Castro A.
dc.date.accessioned	2020-09-02T22:24:09Z
dc.date.available	2020-09-02T22:24:09Z
dc.date.issued	2017
dc.identifier	10.1039/c7cp01870c
dc.identifier.citation	19, 20, 12633-12636
dc.identifier.issn	14639076
dc.identifier.uri	https://hdl.handle.net/20.500.12728/5517
dc.description	A direct correlation between π- and spherical aromaticity of the aromatic structures was established by showing that they shared a characteristic shielding cone, resulting from a specific orientation of the applied field. Herein, we revealed the presence of a related long-range shielding cone in spherical aromatic species that was demonstrated through C20, C32, C50, and C60 Hirsh aromatic fullerenes. It was found that while for planar aromatics, the cone is reserved only for a perpendicularly applied field, for spherical aromatic compounds, the three-dimensional cage allows the formation of a shielding cone according to the given orientation of the external field. © 2017 the Owner Societies.
dc.language.iso	en
dc.publisher	Royal Society of Chemistry
dc.title	The shielding cone in spherical aromatic structures: Insights from models for spherical 2(N + 1)2 aromatic fullerenes
dc.type	Article

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