Photophysics of tungsten-benzylidyne complexes derived from s-indacene: Synthesis, characterization and DFT studies

dc.contributor.author	Morales-Verdejo C.A.
dc.contributor.author	Zarate X.
dc.contributor.author	Schott E.
dc.contributor.author	Correa S.
dc.contributor.author	Martinez-Díaz I.
dc.date.accessioned	2020-09-02T22:23:40Z
dc.date.available	2020-09-02T22:23:40Z
dc.date.issued	2015
dc.identifier	10.1039/c4ra16874g
dc.identifier.citation	5, 32, 25594-25602
dc.identifier.issn	20462069
dc.identifier.uri	https://hdl.handle.net/20.500.12728/5441
dc.description	The photophysics of the mono- and homobimetallic complexes of tungsten-benzylidyne derived from s-indacene have been examined by using absorption and emission. Theoretical calculations of these compounds were carried out to gain further understanding of these novel molecular systems. Consistent with this prediction, each of the complexes displays a weak, mid-visible absorption band which is attributed to the d → π∗ transition. The tungsten complexes also exhibit luminescence with a lifetime in the 5-6 ns regime. This journal is © The Royal Society of Chemistry.
dc.language.iso	en
dc.publisher	Royal Society of Chemistry
dc.title	Photophysics of tungsten-benzylidyne complexes derived from s-indacene: Synthesis, characterization and DFT studies
dc.type	Article

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