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B10M2 (M = Rh, Ir): Finally a stable boron-based icosahedral cluster

dc.contributor.authorLiang W.-Y.
dc.contributor.authorBarroso J.
dc.contributor.authorJalife S.
dc.contributor.authorOrozco-Ic M.
dc.contributor.authorZarate X.
dc.contributor.authorDong X.
dc.contributor.authorCui Z.-H.
dc.contributor.authorMerino G.
dc.date.accessioned2020-09-02T22:21:44Z
dc.date.available2020-09-02T22:21:44Z
dc.date.issued2019
dc.identifier10.1039/c9cc03732b
dc.identifier.citation55, 52, 7490-7493
dc.identifier.issn13597345
dc.identifier.urihttps://hdl.handle.net/20.500.12728/5078
dc.descriptionThe putative global minimum of clusters with formula B10M2 (M = Rh, Ir) corresponds to icosahedral structures formed by two alternately stacked B5 rings with the metals located at the top and bottom vertices. These structures are the closest approximation of molecular clusters to the elusive icosahedral boron. A detailed analysis of the chemical bonding revealed that the covalent character between the transition metal and the boron framework as well as the strong delocalization throughout the structure enhances the stabilization of the icosahedral form. © The Royal Society of Chemistry 2019.
dc.language.isoen
dc.publisherRoyal Society of Chemistry
dc.titleB10M2 (M = Rh, Ir): Finally a stable boron-based icosahedral cluster
dc.typeArticle


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