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Self-association of 5,10,15,20-tetrakis-(4-sulfonatophenyl)-porphyrin tuned by poly(decylviologen) and sulfobutylether-β-cyclodextrin
dc.contributor.author | Flores M.E. | |
dc.contributor.author | Sano N. | |
dc.contributor.author | Araya-Hermosilla R. | |
dc.contributor.author | Shibue T. | |
dc.contributor.author | Olea A.F. | |
dc.contributor.author | Nishide H. | |
dc.contributor.author | Moreno-Villoslada I. | |
dc.date.accessioned | 2020-09-02T22:17:52Z | |
dc.date.available | 2020-09-02T22:17:52Z | |
dc.date.issued | 2015 | |
dc.identifier | 10.1016/j.dyepig.2014.07.015 | |
dc.identifier.citation | 112, , 262-273 | |
dc.identifier.issn | 01437208 | |
dc.identifier.uri | https://hdl.handle.net/20.500.12728/4481 | |
dc.description | With the aim of achieving supramolecular structures containing dyes with controlled state of aggregation, the formation of ternary complexes between 5,10,15,20-tetrakis-(4-sulfonatophenyl)-porphyrin, poly(decylviologen), and sulfobutylether-β-cyclodextrin at low excess of the cyclodextrin is described. By controlling the stoichiometry of the reactants, both non-fluorescent H-aggregates of the dye and stabilized fluorescent monomers may be obtained. The dye undergoes self-aggregation in the presence of the flexible, cationic polymer, and by addition of the negatively charged cyclodextrin the aggregates are cleaved. The cyclodextrin primarily induces the inclusion of 5,10,15,20-tetrakis-(4-sulfonatophenyl)-porphyrin in its cavity, and the ensemble is stabilized by the polymer by means of electrostatic, hydrophobic, and/or aromatic-aromatic interactions. The ternary complex thus produced tends to nanofiber formation, as seen by FE-TEM. © 2014 Elsevier Ltd. All rights reserved. | |
dc.language.iso | en | |
dc.publisher | Elsevier Ltd | |
dc.subject | 5,10,15,20-Tetrakis-(4-sulfonatophenyl)-porphyrin | |
dc.subject | Kinetics | |
dc.subject | Molecular assembly | |
dc.subject | Poly(decylviologen) | |
dc.subject | Sulfobutylether-β- cyclodextrin | |
dc.subject | Ternary complex | |
dc.subject | Agglomeration | |
dc.subject | Aggregates | |
dc.subject | Aromatic compounds | |
dc.subject | Association reactions | |
dc.subject | Enzyme kinetics | |
dc.subject | Fluorescence | |
dc.subject | Porphyrins | |
dc.subject | Aromatic-aromatic interactions | |
dc.subject | Cationic polymers | |
dc.subject | Molecular assembly | |
dc.subject | Negatively charged | |
dc.subject | Poly(decylviologen) | |
dc.subject | Self-associations | |
dc.subject | Supramolecular structure | |
dc.subject | Ternary complex | |
dc.subject | Cyclodextrins | |
dc.title | Self-association of 5,10,15,20-tetrakis-(4-sulfonatophenyl)-porphyrin tuned by poly(decylviologen) and sulfobutylether-β-cyclodextrin | |
dc.type | Article |