Oxidation facility by a temperature dependence on the metal noble nanostructured M°/MxOy phase products using a solid state method: The case of Pd

dc.contributor.author	Díaz C.
dc.contributor.author	Valenzuela M.L.
dc.contributor.author	Rios C.
dc.contributor.author	Segovia M.
dc.date.accessioned	2020-09-02T22:16:47Z
dc.date.available	2020-09-02T22:16:47Z
dc.date.issued	2016
dc.identifier	10.4067/S0717-97072016000400024
dc.identifier.citation	61, 4, 3273-3276
dc.identifier.issn	07179324
dc.identifier.uri	https://hdl.handle.net/20.500.12728/4336
dc.description	Pyrolysis at 800°C under air of the macromolecular precursor Chitosan· (PdCl2)n and PS-co-4-PVP·(PdCl2)n in solid state afford the mixture phases Pt/PdO depending on the molar ratio metal /polymer. For the 1:1 Chitosan· (PdCl2)n and PS-co-4-PVP· (PdCl2)n precursors the pure phase PdO was obtained while that for another molar ratios 1:5 and 1:10, the mixture phase Pt/PdO were obtained. For the 1:10 PS-co-4-PVP· (PdCl2)n precursor the core/shell PdO@Pd nanoparticles as small as 4 nm were observed. Optical properties for the PdO indicate an insulator behavior.
dc.language.iso	en
dc.publisher	Sociedad Chilena de Quimica
dc.title	Oxidation facility by a temperature dependence on the metal noble nanostructured M°/MxOy phase products using a solid state method: The case of Pd
dc.type	Article

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