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Solid-state synthesis of pure and doped lanthanide oxide nanomaterials by using polymer templates. Study of their luminescent properties
dc.contributor.author | Diaz C. | |
dc.contributor.author | Valenzuela M.L. | |
dc.contributor.author | García C. | |
dc.contributor.author | de la Campa R. | |
dc.contributor.author | Presa Soto A. | |
dc.date.accessioned | 2020-09-02T22:16:46Z | |
dc.date.available | 2020-09-02T22:16:46Z | |
dc.date.issued | 2017 | |
dc.identifier | 10.1016/j.matlet.2017.07.112 | |
dc.identifier.citation | 209, , 111-114 | |
dc.identifier.issn | 0167577X | |
dc.identifier.uri | https://hdl.handle.net/20.500.12728/4326 | |
dc.description | We herein reports the solid-state synthesis of pure and doped lanthanide oxides by using polymeric materials (chitosan and polystyrene-co-poly(4-vinylpyridine), PS-co-P4VP) as a solid template. Lanthanide nanomaterials are prepared in two-step methodology combining both solution and solid procedures. The first involves the synthesis of macromolecular complexes Chitosan·[M(NO3)3//M′(NO3)3] and PS-co-P4VP·[M(NO3)3//M′(NO3)3] (M = La, Pr; M′ = Eu); and the second consists in the pyrolysis at 800 °C of the as-prepared solid macromolecular complexes. The pyrolytic products were characterized by X-ray diffraction, SEM-EDS, TEM, and HR-TEM. Whereas similar particle size distribution in average (ca. 25 nm) was observed with both polymer templates, a higher degree of crystallinity was obtained by using PS-co-P4VP. Importantly, the emission luminescent intensity of the doped pyrolytic oxides, La2O3//Eu2O3 and PrO1,83//Eu2O3, is not quenched despite the presence of dopant. Thus, the as-prepared doped oxides exhibit an enhanced Eu3+ emission originated from the 5D0 → 7Fn (n = 1, 2, 3, 4) transitions, which is more intense for the PS-co-P4VP template. This synthetic methodology base on the pyrolysis of polymeric complexes can be considered as a general and straightforward methodology leading to pure and Eu3+-doped nanostructured lanthanide oxide. © 2017 Elsevier B.V. | |
dc.language.iso | en | |
dc.publisher | Elsevier B.V. | |
dc.subject | Chitosan | |
dc.subject | Europium-doped | |
dc.subject | Lanthanide oxide | |
dc.subject | Polymer-templated | |
dc.subject | Chitin | |
dc.subject | Chitosan | |
dc.subject | Doping (additives) | |
dc.subject | Europium | |
dc.subject | Luminescence | |
dc.subject | Macromolecules | |
dc.subject | Nanostructured materials | |
dc.subject | Particle size | |
dc.subject | Particle size analysis | |
dc.subject | Pyrolysis | |
dc.subject | Rare earth elements | |
dc.subject | Synthesis (chemical) | |
dc.subject | X ray diffraction | |
dc.subject | Degree of crystallinity | |
dc.subject | Europium-doped | |
dc.subject | Lanthanide oxide | |
dc.subject | Luminescent intensity | |
dc.subject | Macromolecular complexes | |
dc.subject | Poly(4-vinyl pyridine) | |
dc.subject | Synthetic methodology | |
dc.subject | Templated | |
dc.subject | Polymers | |
dc.title | Solid-state synthesis of pure and doped lanthanide oxide nanomaterials by using polymer templates. Study of their luminescent properties | |
dc.type | Article |