Variation of through-space magnetic response properties upon the formation of cation-π interactions: A survey of [Ag(η-CH2CH2)3]+via DFT calculations
Autor
Camacho Gonzalez J.
Morales-Verdejo C.
Muñoz-Castro A.
Resumen
[Ag(η-CH2CH2)3]+ is a prototypical metal-olefin complex displaying cation-π interactions. Herein, we describe the through-space magnetic response to better understand the influence of the metallic center on the organic ligands. The analysis reveals the short- and long-range anisotropic effects produced by Ag+, which influence the C2H4 ligands. This journal is © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2015.
Colecciones
Ítems relacionados
Mostrando ítems relacionados por Título, autor o materia.
-
Article
Influence of Ag+ on the Magnetic Response of [2.2.2]Paracyclophane: NMR Properties of a Prototypical Organic Host for Cation Binding Based on DFT Calculations (2020)
MacLeodcarey D.; Gomez T.; Morales-Verdejo C.; Muñoz-Castro A. (Wiley-VCH Verlag, 2015) -
Article
Helicenes as Molecular Tweezers in the Formation of Cation−π Complexes. Bonding and Circular Dichroism Properties from Relativistic DFT Calculations (2020)
Ortolan A.O.; Caramori G.F.; Parreira R.L.T.; Muñoz-Castro A. (Wiley-VCH Verlag, 2018) -
Article
[2.2.2]Paracyclophane, preference for η6 or η18 coordination mode including Ag(I) and Sn(II): A survey into the cation-π interaction nature through relativistic DFT calculations (2020)
Ulloa C.O.; Ponce-Vargas M.; De Mattos Piccoli R.; Caramori G.F.; Frenking G.; Muñoz-Castro A. (Royal Society of Chemistry, 2015)