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Revisiting the racemization mechanism of helicenes

dc.contributor.authorBarroso J.
dc.contributor.authorCabellos J.L.
dc.contributor.authorPan S.
dc.contributor.authorMurillo F.
dc.contributor.authorZarate X.
dc.contributor.authorFernandez-Herrera M.A.
dc.contributor.authorMerino G.
dc.date.accessioned2020-09-02T22:13:02Z
dc.date.available2020-09-02T22:13:02Z
dc.date.issued2017
dc.identifier10.1039/c7cc08191j
dc.identifier.citation54, 2, 188-191
dc.identifier.issn13597345
dc.identifier.urihttps://hdl.handle.net/20.500.12728/3705
dc.descriptionHerein we propose a general mechanism for the racemization of [n]helicenes up to n = 24. It is a concerted process for n = 4-7, but a multi-step mechanism is followed for n ≥ 8, involving 2n - 14 intermediates. The changes in the barriers are a delicate consequence of the steric hindrance and the π-interactions. © The Royal Society of Chemistry 2018.
dc.language.isoen
dc.publisherRoyal Society of Chemistry
dc.titleRevisiting the racemization mechanism of helicenes
dc.typeArticle


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