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Synthesis, characterization and molecular dynamics simulation of dendronized poly(3,5-diphthalimidoalkylphenyl methacrylate)s

dc.contributor.authorAlvarado N.
dc.contributor.authorAlegría L.
dc.contributor.authorSandoval C.
dc.contributor.authorGargallo L.
dc.contributor.authorLeiva A.
dc.contributor.authorRadic D.
dc.date.accessioned2020-09-02T22:11:09Z
dc.date.available2020-09-02T22:11:09Z
dc.date.issued2016
dc.identifier10.14314/polimery.2016.010
dc.identifier.citation61, 1, 10-15
dc.identifier.issn00322725
dc.identifier.urihttps://hdl.handle.net/20.500.12728/3542
dc.descriptionDendronized methacrylates containing 3,5-diphthalimidoalkylphenyl moieties (with ethyl, propyl or butyl spacer groups) were synthesized. These monomers were then polymerized using radical polymerization. Monomers and polymers were characterized using Fourier transform infrared spectroscopy (FT-IR) and nuclear magnetic resonance methods (1H NMR and 13C NMR). Molecular weight was estimated by multi-angle static light scattering (MALS). Molecular dynamics simulation was performed to evaluate the conformational radius of gyration (Rg) and the end-to-end distance (ree). Different spatial arrangements depending on the length of the spacer group are observed.
dc.language.isoen
dc.publisherInstytut Chemii Przemyslowej
dc.subjectDendronized polymers
dc.subjectEnd-to-end distance
dc.subjectMolecular dynamics simulation
dc.subjectPoly(phtalimidoalkyl methacrylate)
dc.subjectRadius of gyration
dc.subjectSpacer groups
dc.subjectFourier transform infrared spectroscopy
dc.subjectLight scattering
dc.subjectMonomers
dc.subjectNuclear magnetic resonance
dc.subjectNuclear magnetic resonance spectroscopy
dc.subjectDendronized polymers
dc.subjectEnd-to-end distances
dc.subjectMolecular dynamics simulations
dc.subjectPoly(phtalimidoalkyl methacrylate)
dc.subjectRadius of gyration
dc.subjectSpacer groups
dc.subjectMolecular dynamics
dc.titleSynthesis, characterization and molecular dynamics simulation of dendronized poly(3,5-diphthalimidoalkylphenyl methacrylate)s
dc.typeArticle


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