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Usefulness of the Cl/Br ratio to identify the effect of reverse osmosis treated waters on groundwater systems
dc.contributor.author | Alcalá F.J. | |
dc.date.accessioned | 2020-09-02T22:11:03Z | |
dc.date.available | 2020-09-02T22:11:03Z | |
dc.date.issued | 2019 | |
dc.identifier | 10.1016/j.desal.2019.114102 | |
dc.identifier.citation | 470, , - | |
dc.identifier.issn | 00119164 | |
dc.identifier.uri | https://hdl.handle.net/20.500.12728/3503 | |
dc.description | The chloride-to-bromide molar ratio (R ≡ Cl/Br) is widely used in tracing groundwater salinity. Less experience exists on how some industrial processes such as the reverse osmosis (RO) water treatment modify the R value of desalinated water (P) and reject brine (T), and even less on how distinctive for hydrogeological applications the R changes are. This paper assesses the Cl/Br ratio usefulness to identify the effect of P and T on groundwater systems. First, the experimental R changes produced in P and T during standard RO operations and treatments of raw (I) seawater, brackish groundwater, and tertiary-treated domestic wastewater in nine RO plants (three in Gran Canaria Island and six in south-eastern continental Spain) were determined by means of the XP = RP/RI (R change in P) and XT = RT/RI (R change in T) ratios. XP and XT were respectively 0.90 and 1.07 for treatment 1 (weak pre-acidification) in one RO plant, 0.82 ± 0.09 and 0.94 ± 0.05 for treatment 2 (weak pre-acidification and weak pre-chlorination) in five RO plants, 0.63 and 0.97 for treatment 3 (moderate pre-acidification and strong pre-chlorination) in one RO plant, and 3.21 ± 2.02 and 1.00 ± 0.00 for treatment 4 (post-chlorination) in two RO plants. P was for irrigation (treatments 1 to 3) and for domestic use (treatment 4). Latter, the experimental XP and XT ratios were input data for six theoretical mixing scenarios aimed at showing how groundwater R changes in response to progressive contributions of P and T produced from different I water. The Cl/Br ratio enables to identify the effect of P from treatments 3 and 4, is scarcely effective for treatments 1 and 2, and is especially useful when P produced from seawater is used in other aquifer having different R. The Cl/Br ratio did not clearly identify T from any treatment. © 2019 Elsevier B.V. | |
dc.language.iso | en | |
dc.publisher | Elsevier B.V. | |
dc.subject | Chloride-to-bromide ratio | |
dc.subject | Desalinated water | |
dc.subject | Groundwater mixing scenarios | |
dc.subject | Groundwater quality | |
dc.subject | Reject brine | |
dc.subject | Reverse osmosis | |
dc.subject | Acidification | |
dc.subject | Aquifers | |
dc.subject | Chlorination | |
dc.subject | Chlorine compounds | |
dc.subject | Groundwater | |
dc.subject | Groundwater resources | |
dc.subject | Mixing | |
dc.subject | Molar ratio | |
dc.subject | Reverse osmosis | |
dc.subject | Seawater effects | |
dc.subject | Wastewater treatment | |
dc.subject | Water filtration | |
dc.subject | Water quality | |
dc.subject | Brackish ground water | |
dc.subject | Chloride-to-bromide ratio | |
dc.subject | Desalinated water | |
dc.subject | Domestic wastewater | |
dc.subject | Groundwater mixing | |
dc.subject | Groundwater salinities | |
dc.subject | Groundwater system | |
dc.subject | Industrial processs | |
dc.subject | Industrial water treatment | |
dc.subject | aquifer | |
dc.subject | brine | |
dc.subject | bromide | |
dc.subject | chloride | |
dc.subject | desalination | |
dc.subject | experimental study | |
dc.subject | groundwater pollution | |
dc.subject | mixing | |
dc.subject | reverse osmosis | |
dc.subject | wastewater treatment | |
dc.subject | Canary Islands | |
dc.subject | Gran Canaria | |
dc.subject | Las Palmas | |
dc.subject | Spain | |
dc.title | Usefulness of the Cl/Br ratio to identify the effect of reverse osmosis treated waters on groundwater systems | |
dc.type | Article |