ListarInvestigación y Desarrollo por tema "Aromaticity"
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Article
Aromaticity of ortho and meta 8-Cycloparaphenylene and Their Dications: Induced Magnetic Field Analysis with Localized and Delocalized Orbitals in Strained Nanohoops (2021)
(John Wiley and Sons Inc, 2021)Dications of cycloparaphenyles ([n]CPPs) are known to exhibit in-plane global aromaticity, contained in a nanobelt structure. Recently synthesized ortho and meta isomers of [n]CPPs break the radial symmetry of π structure ... -
Article
Aromaticity Survival in Hydrofullerenes: The Case of C66H4 with Its π-Aromatic Circuits (2020)
(Wiley-VCH Verlag, 2020-10-22)The isolated-pentagon rule (IPR) is a determining structural feature that accounts for hollow fullerene stabilization and properties related to Cn (n≥60) cages. The recent characterization of an unprecedented non-IPR ... -
Article
[As3M(As3Pb3)]3− (M = Nb, Ta): Ternary Heterometallic Clusters with Early Transition Metal Atoms and Aromatic [Pb3]2− (2021)
(Shanghai Institute of Organic Chemistry, 2021)Two ternary clusters, [As3Nb(As3Pb3)]3− 1 and [As3Ta(As3Pb3)]3− 2, were directly extracted from “K8NbPbAs5” and “K8TaPbAs5” intermetallic solid in the presence of ethylenediamine and 2.2.2-crypt, respectively. Both 1 and ... -
Article
Bridging Aromatic/Antiaromatic Units: Recent Advances in Aromaticity and Antiaromaticity in Main-group and Transition-Metal Clusters from Bonding and Magnetic Analyses (2021)
(John Wiley and Sons Inc, 2021)Synthetic exploration and theoretical characterization of metal clusters are actively developing branches of modern inorganic chemistry. Advances in these areas constantly expand the rich structural diversity of viable ... -
Article
Unique magnetic shielding and bonding in Pnicogen nortricyclane Zintl clusters (2020)
(Elsevier B.V., 2020)