Listar Investigación y Desarrollo por autor "Cañete M., Alvaro"
Mostrando ítems 1-3 de 3
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Article
Cucurbit[7]uril limits the binding of coumarin bearing alkyl-acetoacetate with mercury and stimulates the desulphurisation reaction of its sulphur analog (2020)
Aliaga, Margarita E.; Pávez, Paulina; Quintero, Guillermo; Droguett, Kevin; Cañete M., Alvaro; Santos, José (Taylor and Francis Ltd., 2020-12-15)The inclusion of 7-diethylamino-coumarin derivatives, bearing an ethyl acetoacetate (CAM1) and a methyl β-ketodithioester moiety (CAM2) in the cavity of cucurbit[7]uril (CB7), leads to different interaction forms with ... -
Article
Spectral probe for electron transfer and addition reactions of azide radicals with substituted quinoxalin-2-ones in aqueous solutions (2021)
Skotnicki, Konrad; Ostrowski, SŁawomir; Dobrowolski, Jan Cz Z.; de la Fuente, Julio R.; Cañete M., Alvaro; Bobrowski, Krzysztof (MDPI AG, 2021-01-02)The azide radical (N3●) is one of the most important one-electron oxidants used extensively in radiation chemistry studies involving molecules of biological significance. Generally, it was assumed that N3● reacts in aqueous ... -
Article
Supramolecular Control of Reactivity toward Hydrolysis of 7-Diethylaminocoumarin Schiff Bases by Cucurbit[7]uril Encapsulation (2021)
Alcázar, Jackson J.; Geue, Niklas; Valladares, Verónica; Cañete M., Alvaro; Pérez, Edwin G.; García-Río, Luís; Santos, José; Aliaga, Margarita E. (American Chemical Society, 2021)A series of aromatic Schiff bases, featuring 7-diethylamino-coumarin and with five different substituents at an adjacent phenyl ring, were synthesized and characterized. With the aim of assessing the stability of these ...