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Alkali-driven selectivity of products on carbon-supported Ni-based catalysts during the HDO of guaiacol
dc.contributor.author | Matos, Juan | |
dc.contributor.author | Samudio-González, Diana | |
dc.contributor.author | Blanco, Elodie | |
dc.contributor.author | Poon, Po S. | |
dc.contributor.author | Escalona, Néstor | |
dc.date.accessioned | 2024-07-23T19:34:17Z | |
dc.date.available | 2024-07-23T19:34:17Z | |
dc.date.issued | 2024 | |
dc.identifier | 10.1016/j.fuel.2024.132442 | |
dc.identifier.issn | 00162361 | |
dc.identifier.uri | https://hdl.handle.net/20.500.12728/11592 | |
dc.description.abstract | The catalytic hydrodeoxygenation (HDO) of guaiacol as a representative bio-oil molecule was studied using a series of carbon-supported Ni-based catalysts. The promoter effect of alkali metals (Ca and Mg) on the catalytic activity and selectivity was verified. Catalysts were prepared by wetness incipient method and N2 gas adsorption/desorption isotherms, X-ray diffraction, reduction/desorption temperature-programed, and CO chemisorption analysis were performed to characterize the catalysts. In terms of the initial reaction-rate catalysts with 1 wt% alkali-promotors showed an increase in the activity up to ca. 1.4 and 1.2 times higher on Ni-Ca(1 %)/AC and Ni-Mg(1 %)/AC, respectively, compared to Ni/AC catalyst. The increase to 5 wt% in alkali promotors slightly reduced the initial activity of Ni. However, the turn-over frequencies estimated showed higher values when alkali content is increased from 1 wt% to 5 wt%. These apparent contradictorial results suggest the formation of new actives sites along reaction, probably constituted by a mixture of oxides NiO-CaO and NiO-MgO. The selectivity of products showed remarkable changes due to the presence of alkali-promotors and a mechanism or reaction is proposed based on the kinetics of formation and evolution of products. Mg-promoted led to the formation of cyclohexane. On the contrary, Ca-promoted catalysts led the mechanism to representative benzene yields. This is remarkable result regarding the efficiency of a HDO biorefinery. In general, it can be concluded that Ni-based catalysts promoted with alkali metals are an economical alternative for the catalytic conversion of representative target molecules from a bio-oil feed. © 2024 Elsevier Ltd | es_ES |
dc.language.iso | en | es_ES |
dc.publisher | Elsevier Ltd | es_ES |
dc.subject | Alkali-promotors | es_ES |
dc.subject | Biorefinery | es_ES |
dc.subject | Guaiacol conversion | es_ES |
dc.subject | Ni-based catalysts | es_ES |
dc.subject | Selectivity | es_ES |
dc.title | Alkali-driven selectivity of products on carbon-supported Ni-based catalysts during the HDO of guaiacol | es_ES |
dc.type | Article | es_ES |