Listar por autor "Xu, Honglei"
Mostrando ítems 1-3 de 3
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Article
A sandwich-type cluster containing Ge@Pd3 planar fragment flanked by aromatic nonagermanide caps (2020)
Xu, Honglei; Tkachenko, Nikolay V.; Wang, Zichuan; Chen, Weixing; Qiao, Lei; Muñoz-Castro, Alvaro; Boldyrev, Alexander I.; Sun, Zhongming (Nature Research, 2020-12-01)Sandwich-type clusters with the planar fragment containing a heterometallic sheet have remained elusive. In this work, we introduce the [K(2,2,2-crypt)]4{(Ge9)2[η6-Ge(PdPPh3)3]} complex that contains a heterometallic ... -
Article
[Sn8]6−-Bridged Mixed-Valence ZnI/ZnII in {[K2ZnSn8(ZnMes)]2}4− Inverse Sandwich-Type Cluster Supported by a ZnI−ZnI Bond (2021)
Xu, Honglei; Tkachenko, Nikolay V.; Muñoz-Castro, Alvaro; Boldyrev, Alexander I.; Sun, Zhongming (John Wiley and Sons Inc, 2021)Since [Sn8]6− was discovered from the solid-state phase in 2000, its solution chemistry has been elusive due to the high charges and chemical activity. Herein, we report the synthesis and characterization of an inverse ... -
Article
Symmetry collapse due to the presence of multiple local aromaticity in Ge244− (2022)
Xu, Honglei; Tkachenko, Nikolay V.; Szczepanik, Dariusz W.; Popov, Ivan A.; Muñoz-Castro, Álvaro; Boldyrev, Alexander I.; Sun, Zhongming (Nature Research, 2022-12)Understanding the structural changes taking place during the assembly of single atoms leading to the formation of atomic clusters and bulk materials remains challenging. The isolation and theoretical characterization of ...